在某一特定的化学反应中,每 2 克 与 1 克 结合并转化为 3 克 。设 、 和 分别表示在时间 (以分钟为单位)时存在的 、 和 的质量(以克为单位)。根据质量作用定律, 对 的变化率与 和 的乘积成正比。初始时,, 且 。
- (i)
证明 ,其中 是一个正常数。
- (ii)
经观察,当 时,。
求当 时的 值,结果保留两位小数。
- (iii)
当 很大时, 会发生什么变化?
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完整解法
12(i)
1. Express the remaining masses of $U$ and $V$ in terms of $w$.
Since 2 grams of and 1 gram of produce 3 grams of , the masses of and consumed to produce grams of are and respectively.
Thus, the remaining masses at time are:
2. Use the law of mass action to write the differential equation.
The rate of change of is proportional to . Let be the constant of proportionality:
3. Factorise the expression into the required form and show that $k > 0$.
Let , giving .
Since is being formed initially, the rate of change is positive () when .
Hence shown.
(shown)
12(ii)
1. Separate variables and apply partial fractions to prepare for integration.
Using partial fractions:
When ,
When ,
2. Integrate both sides to obtain the general solution.
Since starts at and must be less than (the limiting mass), . We can rewrite it without the modulus sign as:
3. Use the initial condition to find the constant of integration $C$.
Given that initially when :
Substituting back into the equation:
4. Apply the condition at $t = 5$ to evaluate the parameter $k$.
When , :
5. Substitute $t = 20$ into the specific equation to solve for $w$.
When :
12(iii)
1. Identify the behaviour of the solution's exponential term as $t \to \infty$.
From the integration in part (ii), the relationship between and can be expressed as:
Since is a positive constant, as , the exponent , and therefore .
(Alternatively, if was made the subject: , as , )
2. Deduce the limiting value of $w$.
For to approach , the denominator must approach :
(From the alternative expression: )
Thus, as becomes very large, the mass approaches grams.
approaches (or the mass of approaches )
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