在某一特定的化学反应中,每 2 克 UU 与 1 克 VV 结合并转化为 3 克 WW。设 uu、vv 和 ww 分别表示在时间 tt(以分钟为单位)时存在的 UU、VV 和 WW 的质量(以克为单位)。根据质量作用定律,ww 对 tt 的变化率与 uu 和 vv 的乘积成正比。初始时,u=40u=40,v=50v=50 且 w=0w=0。

  1. (i)

    证明 dwdt=k(w−60)(w−150)\dfrac{dw}{dt} = k(w-60)(w-150),其中 kk 是一个正常数。

  2. (ii)

    经观察,当 t=5t = 5 时,w=10w = 10。

    求当 t=20t = 20 时的 ww 值,结果保留两位小数。

  3. (iii)

    当 tt 很大时,ww 会发生什么变化?

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完整解法

12(i)

1. Express the remaining masses of $U$ and $V$ in terms of $w$.

Since 2 grams of UU and 1 gram of VV produce 3 grams of WW, the masses of UU and VV consumed to produce ww grams of WW are 23w\frac{2}{3}w and 13w\frac{1}{3}w respectively.
Thus, the remaining masses at time tt are:
u=40−23wu = 40 - \frac{2}{3}w
v=50−13wv = 50 - \frac{1}{3}w

2. Use the law of mass action to write the differential equation.

The rate of change of ww is proportional to uvuv. Let k1k_1 be the constant of proportionality:
dwdt=k1uv=k1(40−23w)(50−13w)\frac{dw}{dt} = k_1 u v = k_1 \left(40 - \frac{2}{3}w\right)\left(50 - \frac{1}{3}w\right)

3. Factorise the expression into the required form and show that $k > 0$.

dwdt=k1[−23(w−60)][−13(w−150)]\frac{dw}{dt} = k_1 \left[ -\frac{2}{3}(w - 60) \right] \left[ -\frac{1}{3}(w - 150) \right]
dwdt=29k1(w−60)(w−150)\frac{dw}{dt} = \frac{2}{9}k_1 (w - 60)(w - 150)
Let k=29k1k = \frac{2}{9}k_1, giving dwdt=k(w−60)(w−150)\frac{dw}{dt} = k(w - 60)(w - 150).
Since WW is being formed initially, the rate of change is positive (dwdt>0\frac{dw}{dt} > 0) when w=0w=0.
k(0−60)(0−150)>0  ⟹  9000k>0  ⟹  k>0k(0 - 60)(0 - 150) > 0 \implies 9000k > 0 \implies k > 0
Hence shown.

答案

dwdt=k(w−60)(w−150)\frac{dw}{dt} = k(w-60)(w-150) (shown)

12(ii)

1. Separate variables and apply partial fractions to prepare for integration.

dwdt=k(w−60)(w−150)\frac{dw}{dt} = k(w-60)(w-150)
∫1(w−60)(w−150) dw=∫k dt\int \frac{1}{(w-60)(w-150)} \,dw = \int k \,dt
Using partial fractions:
1(w−60)(w−150)=Aw−60+Bw−150\frac{1}{(w-60)(w-150)} = \frac{A}{w-60} + \frac{B}{w-150}
1=A(w−150)+B(w−60)1 = A(w-150) + B(w-60)
When w=60w = 60, −90A=1  ⟹  A=−190-90A = 1 \implies A = -\frac{1}{90}
When w=150w = 150, 90B=1  ⟹  B=19090B = 1 \implies B = \frac{1}{90}
190∫(1w−150−1w−60) dw=∫k dt\frac{1}{90} \int \left( \frac{1}{w-150} - \frac{1}{w-60} \right) \,dw = \int k \,dt

2. Integrate both sides to obtain the general solution.

190(ln⁡∣w−150∣−ln⁡∣w−60∣)=kt+C\frac{1}{90} (\ln|w-150| - \ln|w-60|) = kt + C
190ln⁡∣w−150w−60∣=kt+C\frac{1}{90} \ln\left|\frac{w-150}{w-60}\right| = kt + C
Since ww starts at 00 and must be less than 6060 (the limiting mass), w−150w−60>0\frac{w-150}{w-60} > 0. We can rewrite it without the modulus sign as:
190ln⁡(150−w60−w)=kt+C\frac{1}{90} \ln\left(\frac{150-w}{60-w}\right) = kt + C

3. Use the initial condition to find the constant of integration $C$.

Given that initially w=0w = 0 when t=0t = 0:
190ln⁡(150−060−0)=k(0)+C\frac{1}{90} \ln\left(\frac{150-0}{60-0}\right) = k(0) + C
C=190ln⁡(15060)=190ln⁡(2.5)C = \frac{1}{90} \ln\left(\frac{150}{60}\right) = \frac{1}{90} \ln(2.5)
Substituting CC back into the equation:
190ln⁡(150−w60−w)=kt+190ln⁡(2.5)\frac{1}{90} \ln\left(\frac{150-w}{60-w}\right) = kt + \frac{1}{90} \ln(2.5)
ln⁡(150−w60−w)=90kt+ln⁡(2.5)\ln\left(\frac{150-w}{60-w}\right) = 90kt + \ln(2.5)

4. Apply the condition at $t = 5$ to evaluate the parameter $k$.

When t=5t = 5, w=10w = 10:
ln⁡(150−1060−10)=90k(5)+ln⁡(2.5)\ln\left(\frac{150-10}{60-10}\right) = 90k(5) + \ln(2.5)
ln⁡(14050)=450k+ln⁡(2.5)\ln\left(\frac{140}{50}\right) = 450k + \ln(2.5)
450k=ln⁡(2.8)−ln⁡(2.5)=ln⁡(2.82.5)=ln⁡(1.12)450k = \ln(2.8) - \ln(2.5) = \ln\left(\frac{2.8}{2.5}\right) = \ln(1.12)

5. Substitute $t = 20$ into the specific equation to solve for $w$.

When t=20t = 20:
ln⁡(150−w60−w)=90k(20)+ln⁡(2.5)\ln\left(\frac{150-w}{60-w}\right) = 90k(20) + \ln(2.5)
ln⁡(150−w60−w)=4(450k)+ln⁡(2.5)\ln\left(\frac{150-w}{60-w}\right) = 4(450k) + \ln(2.5)
ln⁡(150−w60−w)=4ln⁡(1.12)+ln⁡(2.5)\ln\left(\frac{150-w}{60-w}\right) = 4\ln(1.12) + \ln(2.5)
ln⁡(150−w60−w)=ln⁡(1.124×2.5)\ln\left(\frac{150-w}{60-w}\right) = \ln(1.12^4 \times 2.5)
150−w60−w=1.124×2.5≈3.9338\frac{150-w}{60-w} = 1.12^4 \times 2.5 \approx 3.9338
150−w=3.9338(60−w)150 - w = 3.9338(60 - w)
150−w=236.0279−3.9338w150 - w = 236.0279 - 3.9338w
2.9338w=86.02792.9338w = 86.0279
w≈29.323w \approx 29.323
w=29.32 (to 2 d.p.)w = 29.32 \text{ (to 2 d.p.)}

答案

29.3229.32

12(iii)

1. Identify the behaviour of the solution's exponential term as $t \to \infty$.

From the integration in part (ii), the relationship between ww and tt can be expressed as:
150−w60−w=2.5e90kt\frac{150-w}{60-w} = 2.5 e^{90kt}
Since kk is a positive constant, as t→∞t \to \infty, the exponent 90kt→∞90kt \to \infty, and therefore e90kt→∞e^{90kt} \to \infty.
(Alternatively, if ww was made the subject: w=150−150e−90kt2.5−e−90ktw = \frac{150 - 150e^{-90kt}}{2.5 - e^{-90kt}}, as t→∞t \to \infty, e−90kt→0e^{-90kt} \to 0)

2. Deduce the limiting value of $w$.

For 150−w60−w\frac{150-w}{60-w} to approach ∞\infty, the denominator must approach 00:
60−w→060 - w \to 0
w→60w \to 60
(From the alternative expression: w→150−02.5−0=60w \to \frac{150 - 0}{2.5 - 0} = 60)

Thus, as tt becomes very large, the mass ww approaches 6060 grams.

答案

ww approaches 6060 (or the mass of WW approaches 60 g60\text{ g})

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