In a chemical reaction, a compound XX is formed from two compounds YY and ZZ. The masses in grams of XX, YY and ZZ present at time tt seconds after the start of the reaction are xx, 15−x15 - x and 25−x25 - x respectively. At any time, the rate of formation of XX is proportional to the product of masses of YY and ZZ present at the time. It is given that x=0x = 0 and dxdt=3\frac{\text{d}x}{\text{d}t} = 3 when t=0t = 0. [Continued]

  1. (i)

    Write down a differential equation relating xx and tt and find the value of the constant of proportionality.

  2. (ii)

    Solve the differential equation found in part (i) and obtain an expression for xx in terms of tt.

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Worked solution

11(i)

1. Translate the given problem statement into a differential equation using a constant of proportionality $k$.

The rate of formation of XX is dxdt\frac{\text{d}x}{\text{d}t}. It is proportional to the product of the masses of YY and ZZ, which are (15−x)(15-x) and (25−x)(25-x) respectively.

dxdt=k(15−x)(25−x)\frac{\text{d}x}{\text{d}t} = k(15 - x)(25 - x)

2. Substitute the initial conditions to find the value of $k$.

Given x=0x = 0 and dxdt=3\frac{\text{d}x}{\text{d}t} = 3 when t=0t = 0:
3=k(15−0)(25−0)3 = k(15 - 0)(25 - 0)
3=375k3 = 375k
k=3375=1125k = \frac{3}{375} = \frac{1}{125}

Answer

dxdt=k(15−x)(25−x)\frac{\text{d}x}{\text{d}t} = k(15 - x)(25 - x) and k=1125k = \frac{1}{125}

11(ii)

1. Substitute the constant of proportionality from part (i) and separate the variables.

From part (i), the differential equation is:
dxdt=1125(15−x)(25−x)\frac{\mathrm{d}x}{\mathrm{d}t} = \frac{1}{125}(15-x)(25-x)
Separating the variables:
∫1(15−x)(25−x) dx=∫1125 dt\int \frac{1}{(15-x)(25-x)} \, \mathrm{d}x = \int \frac{1}{125} \, \mathrm{d}t

2. Decompose the rational expression using partial fractions.

Let 1(15−x)(25−x)≡A15−x+B25−x\frac{1}{(15-x)(25-x)} \equiv \frac{A}{15-x} + \frac{B}{25-x}
1≡A(25−x)+B(15−x)1 \equiv A(25-x) + B(15-x)
Substituting x=15  ⟹  1=10A  ⟹  A=110x = 15 \implies 1 = 10A \implies A = \frac{1}{10}
Substituting x=25  ⟹  1=−10B  ⟹  B=−110x = 25 \implies 1 = -10B \implies B = -\frac{1}{10}
Substitute back into the integral equation:
110∫(115−x−125−x) dx=∫1125 dt\frac{1}{10} \int \left( \frac{1}{15-x} - \frac{1}{25-x} \right) \, \mathrm{d}x = \int \frac{1}{125} \, \mathrm{d}t
∫(115−x−125−x) dx=∫225 dt\int \left( \frac{1}{15-x} - \frac{1}{25-x} \right) \, \mathrm{d}x = \int \frac{2}{25} \, \mathrm{d}t

3. Integrate both sides to find the general solution.

−ln⁡∣15−x∣+ln⁡∣25−x∣=225t+C-\ln|15-x| + \ln|25-x| = \frac{2}{25}t + C
ln⁡∣25−x15−x∣=225t+C\ln\left| \frac{25-x}{15-x} \right| = \frac{2}{25}t + C

4. Apply the initial condition to evaluate the constant of integration.

Given x=0x=0 when t=0t=0:
ln⁡∣25−015−0∣=225(0)+C  ⟹  C=ln⁡(53)\ln\left| \frac{25-0}{15-0} \right| = \frac{2}{25}(0) + C \implies C = \ln\left(\frac{5}{3}\right)
Substituting CC back into the equation:
ln⁡∣25−x15−x∣=225t+ln⁡(53)\ln\left| \frac{25-x}{15-x} \right| = \frac{2}{25}t + \ln\left(\frac{5}{3}\right)

5. Remove the logarithm and use the physical context to determine the sign.

Since compound XX is formed from YY (initial mass 1515 g), the mass xx must be less than 1515. Thus for t≥0t \geq 0, 15−x>015-x > 0 and 25−x>025-x > 0, allowing us to remove the absolute value bars.
25−x15−x=e225t+ln⁡(5/3)\frac{25-x}{15-x} = \mathrm{e}^{\frac{2}{25}t + \ln(5/3)}
25−x15−x=53e225t\frac{25-x}{15-x} = \frac{5}{3}\mathrm{e}^{\frac{2}{25}t}

6. Rearrange the equation to make $x$ the subject.

Cross-multiplying:
3(25−x)=5(15−x)e225t3(25-x) = 5(15-x)\mathrm{e}^{\frac{2}{25}t}
75−3x=75e225t−5xe225t75 - 3x = 75\mathrm{e}^{\frac{2}{25}t} - 5x\mathrm{e}^{\frac{2}{25}t}
Group terms involving xx:
5xe225t−3x=75e225t−755x\mathrm{e}^{\frac{2}{25}t} - 3x = 75\mathrm{e}^{\frac{2}{25}t} - 75
x(5e225t−3)=75(e225t−1)x(5\mathrm{e}^{\frac{2}{25}t} - 3) = 75(\mathrm{e}^{\frac{2}{25}t} - 1)
x=75(e225t−1)5e225t−3x = \frac{75(\mathrm{e}^{\frac{2}{25}t} - 1)}{5\mathrm{e}^{\frac{2}{25}t} - 3}

Answer

x=75(e225t−1)5e225t−3x = \frac{75(\mathrm{e}^{\frac{2}{25}t} - 1)}{5\mathrm{e}^{\frac{2}{25}t} - 3}

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