In a chemical reaction, a compound is formed from two compounds and . The masses in grams of , and present at time seconds after the start of the reaction are , and respectively. At any time, the rate of formation of is proportional to the product of masses of and present at the time. It is given that and when . [Continued]
- (i)
Write down a differential equation relating and and find the value of the constant of proportionality.
- (ii)
Solve the differential equation found in part (i) and obtain an expression for in terms of .
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Worked solution
11(i)
1. Translate the given problem statement into a differential equation using a constant of proportionality $k$.
The rate of formation of is . It is proportional to the product of the masses of and , which are and respectively.
2. Substitute the initial conditions to find the value of $k$.
Given and when :
and
11(ii)
1. Substitute the constant of proportionality from part (i) and separate the variables.
From part (i), the differential equation is:
Separating the variables:
2. Decompose the rational expression using partial fractions.
Let
Substituting
Substituting
Substitute back into the integral equation:
3. Integrate both sides to find the general solution.
4. Apply the initial condition to evaluate the constant of integration.
Given when :
Substituting back into the equation:
5. Remove the logarithm and use the physical context to determine the sign.
Since compound is formed from (initial mass g), the mass must be less than . Thus for , and , allowing us to remove the absolute value bars.
6. Rearrange the equation to make $x$ the subject.
Cross-multiplying:
Group terms involving :
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