The molecular geometry is the three-dimensional arrangement of atoms in a molecule. Fig. 1 shows the molecular geometry of a particular molecule which is of a tetrahedral form with one central atom lying inside the tetrahedron and 4 other atoms at the vertices of the tetrahedron. The points AA, BB, CC and DD represent the 4 vertices of the tetrahedron and are connected to the central atom, which is denoted by the point EE, forming 4 pairs of bonding atoms AEAE, BEBE, CECE and DEDE. The coordinates of AA, BB, CC, DD and EE are given by (2,3,4)(2,3,4), (0,0,3)(0,0,3), (3,0,0)(3,0,0), (0,4,0)(0,4,0) and (1,1,2)(1,1,2) respectively. The plane pp passes through the points AA, BB and CC. The line ll passes through the points DD and EE.

  1. (i)

    Find a cartesian equation of pp.

  2. (ii)

    Find a vector equation of ll and the coordinates of the point of intersection of ll and pp.

  3. (iii)

    Hence, find the shortest distance from point EE to pp.

  4. (iv)

    The bond angle is the angle between any two pairs of bonding atoms, measured in degrees.

    Find the bond angle between bonding atoms AEAE and CECE.

  5. (7)
    1. (ii)

      Hence solve the differential equation xdydx=y+6xyx\frac{\mathrm{d}y}{\mathrm{d}x} = y + 6xy to find yy in terms of xx.

    2. (iii)

      What happens to the number of people infected with the disease if this situation continues after many months?

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Worked solution

6(i)

1. Find two distinct direction vectors parallel to the plane.

Let the origin be OO. The position vectors are OA⃗=(234)\vec{OA} = \begin{pmatrix} 2 \\ 3 \\ 4 \end{pmatrix}, OB⃗=(003)\vec{OB} = \begin{pmatrix} 0 \\ 0 \\ 3 \end{pmatrix}, and OC⃗=(300)\vec{OC} = \begin{pmatrix} 3 \\ 0 \\ 0 \end{pmatrix}.

Find the vectors BC⃗\vec{BC} and BA⃗\vec{BA}:
BC⃗=OC⃗−OB⃗=(300)−(003)=(30−3)\vec{BC} = \vec{OC} - \vec{OB} = \begin{pmatrix} 3 \\ 0 \\ 0 \end{pmatrix} - \begin{pmatrix} 0 \\ 0 \\ 3 \end{pmatrix} = \begin{pmatrix} 3 \\ 0 \\ -3 \end{pmatrix}
BA⃗=OA⃗−OB⃗=(234)−(003)=(231)\vec{BA} = \vec{OA} - \vec{OB} = \begin{pmatrix} 2 \\ 3 \\ 4 \end{pmatrix} - \begin{pmatrix} 0 \\ 0 \\ 3 \end{pmatrix} = \begin{pmatrix} 2 \\ 3 \\ 1 \end{pmatrix}

2. Determine a normal vector to the plane using the cross product.

A normal vector n\mathbf{n} to the plane is given by the cross product BC⃗×BA⃗\vec{BC} \times \vec{BA}:
n=(30−3)×(231)=((0)(1)−(−3)(3)(−3)(2)−(3)(1)(3)(3)−(0)(2))=(9−99)\mathbf{n} = \begin{pmatrix} 3 \\ 0 \\ -3 \end{pmatrix} \times \begin{pmatrix} 2 \\ 3 \\ 1 \end{pmatrix} = \begin{pmatrix} (0)(1) - (-3)(3) \\ (-3)(2) - (3)(1) \\ (3)(3) - (0)(2) \end{pmatrix} = \begin{pmatrix} 9 \\ -9 \\ 9 \end{pmatrix}
To simplify, we can use a scalar multiple of this vector as our normal vector:
n1=19(9−99)=(1−11)\mathbf{n}_1 = \frac{1}{9} \begin{pmatrix} 9 \\ -9 \\ 9 \end{pmatrix} = \begin{pmatrix} 1 \\ -1 \\ 1 \end{pmatrix}

3. Form the cartesian equation of the plane.

Using the normal vector n1=(1−11)\mathbf{n}_1 = \begin{pmatrix} 1 \\ -1 \\ 1 \end{pmatrix} and the point C(3,0,0)C(3, 0, 0), the scalar product equation of the plane pp is r⋅n1=OC⃗⋅n1\mathbf{r} \cdot \mathbf{n}_1 = \vec{OC} \cdot \mathbf{n}_1:
r⋅(1−11)=(300)⋅(1−11)\mathbf{r} \cdot \begin{pmatrix} 1 \\ -1 \\ 1 \end{pmatrix} = \begin{pmatrix} 3 \\ 0 \\ 0 \end{pmatrix} \cdot \begin{pmatrix} 1 \\ -1 \\ 1 \end{pmatrix}
r⋅(1−11)=(3)(1)+(0)(−1)+(0)(1)=3\mathbf{r} \cdot \begin{pmatrix} 1 \\ -1 \\ 1 \end{pmatrix} = (3)(1) + (0)(-1) + (0)(1) = 3
Converting to cartesian form:
x−y+z=3x - y + z = 3

Answer

x−y+z=3x - y + z = 3

6(ii)

1. Find the direction vector of the line $l$ passing through points $D$ and $E$.

The position vectors are OD→=(040)\overrightarrow{OD} = \begin{pmatrix} 0 \\ 4 \\ 0 \end{pmatrix} and OE→=(112)\overrightarrow{OE} = \begin{pmatrix} 1 \\ 1 \\ 2 \end{pmatrix}.

The direction vector of line ll is:
DE→=OE→−OD→=(112)−(040)=(1−32)\overrightarrow{DE} = \overrightarrow{OE} - \overrightarrow{OD} = \begin{pmatrix} 1 \\ 1 \\ 2 \end{pmatrix} - \begin{pmatrix} 0 \\ 4 \\ 0 \end{pmatrix} = \begin{pmatrix} 1 \\ -3 \\ 2 \end{pmatrix}

2. Formulate the vector equation of the line $l$.

Using point DD as the position vector, the vector equation of the line is:
r=(040)+λ(1−32),λ∈R\mathbf{r} = \begin{pmatrix} 0 \\ 4 \\ 0 \end{pmatrix} + \lambda \begin{pmatrix} 1 \\ -3 \\ 2 \end{pmatrix}, \lambda \in \mathbb{R}

3. Derive the cartesian equation of the plane $p$ (required from part i) to find the intersection.

Plane pp passes through A(2,3,4)A(2,3,4), B(0,0,3)B(0,0,3), and C(3,0,0)C(3,0,0).
AB→=(−2−3−1),AC→=(1−3−4)\overrightarrow{AB} = \begin{pmatrix} -2 \\ -3 \\ -1 \end{pmatrix}, \quad \overrightarrow{AC} = \begin{pmatrix} 1 \\ -3 \\ -4 \end{pmatrix}
A normal vector to pp is:
n=AB→×AC→=((−3)(−4)−(−1)(−3)(−1)(1)−(−2)(−4)(−2)(−3)−(−3)(1))=(9−99)=9(1−11)\mathbf{n} = \overrightarrow{AB} \times \overrightarrow{AC} = \begin{pmatrix} (-3)(-4) - (-1)(-3) \\ (-1)(1) - (-2)(-4) \\ (-2)(-3) - (-3)(1) \end{pmatrix} = \begin{pmatrix} 9 \\ -9 \\ 9 \end{pmatrix} = 9 \begin{pmatrix} 1 \\ -1 \\ 1 \end{pmatrix}
Using the normal vector (1−11)\begin{pmatrix} 1 \\ -1 \\ 1 \end{pmatrix} and point B(0,0,3)B(0,0,3), the plane equation is:
r⋅(1−11)=(003)⋅(1−11)=3\mathbf{r} \cdot \begin{pmatrix} 1 \\ -1 \\ 1 \end{pmatrix} = \begin{pmatrix} 0 \\ 0 \\ 3 \end{pmatrix} \cdot \begin{pmatrix} 1 \\ -1 \\ 1 \end{pmatrix} = 3

4. Substitute the vector equation of line $l$ into the equation of plane $p$ to find the parameter $\lambda$ at the intersection.

Substitute r\mathbf{r} of the line into the plane equation:
[(040)+λ(1−32)]⋅(1−11)=3\left[ \begin{pmatrix} 0 \\ 4 \\ 0 \end{pmatrix} + \lambda \begin{pmatrix} 1 \\ -3 \\ 2 \end{pmatrix} \right] \cdot \begin{pmatrix} 1 \\ -1 \\ 1 \end{pmatrix} = 3
(0−4+0)+λ(1−(−3)+2)=3(0 - 4 + 0) + \lambda(1 - (-3) + 2) = 3
−4+6λ=3-4 + 6\lambda = 3
6λ=7  ⟹  λ=766\lambda = 7 \implies \lambda = \frac{7}{6}

5. Calculate the coordinates of the point of intersection.

Substitute λ=76\lambda = \frac{7}{6} back into the vector equation of ll:
r=(040)+76(1−32)=(7/64−21/614/6)=(7/61/27/3)\mathbf{r} = \begin{pmatrix} 0 \\ 4 \\ 0 \end{pmatrix} + \frac{7}{6} \begin{pmatrix} 1 \\ -3 \\ 2 \end{pmatrix} = \begin{pmatrix} 7/6 \\ 4 - 21/6 \\ 14/6 \end{pmatrix} = \begin{pmatrix} 7/6 \\ 1/2 \\ 7/3 \end{pmatrix}
Therefore, the coordinates of the point of intersection are (76,12,73)\left(\frac{7}{6}, \frac{1}{2}, \frac{7}{3}\right).

Answer

Vector equation of ll: r=(040)+λ(1−32),λ∈R\mathbf{r} = \begin{pmatrix} 0 \\ 4 \\ 0 \end{pmatrix} + \lambda \begin{pmatrix} 1 \\ -3 \\ 2 \end{pmatrix}, \lambda \in \mathbb{R}
Coordinates of intersection: (76,12,73)\left(\frac{7}{6}, \frac{1}{2}, \frac{7}{3}\right)

6(iii)

1. Determine the displacement vector $\vec{EF}$ from the central atom $E$ to the intersection point $F$ on the plane $p$.

From part (ii), the intersection point FF corresponds to the parameter λ=16\lambda = \frac{1}{6} when using the line equation r=OE⃗+λDE⃗\mathbf{r} = \vec{OE} + \lambda \vec{DE}.
Thus, the vector from EE to FF is:
EF⃗=16DE⃗=16(1−32)\vec{EF} = \frac{1}{6}\vec{DE} = \frac{1}{6} \begin{pmatrix} 1 \\ -3 \\ 2 \end{pmatrix}

(Note: Alternatively, using the exact coordinates of F(76,12,73)F\left(\frac{7}{6}, \frac{1}{2}, \frac{7}{3}\right) and E(1,1,2)E(1, 1, 2) yields the same displacement EF⃗=OF⃗−OE⃗=(1/6−1/21/3)\vec{EF} = \vec{OF} - \vec{OE} = \begin{pmatrix} 1/6 \\ -1/2 \\ 1/3 \end{pmatrix})

2. Calculate the shortest distance from $E$ to $p$ by projecting $\vec{EF}$ onto the normal vector of $p$.

From part (i), the normal vector to plane pp is n=(1−11)\mathbf{n} = \begin{pmatrix} 1 \\ -1 \\ 1 \end{pmatrix}.
The shortest distance from EE to pp is the length of the projection of EF⃗\vec{EF} onto n\mathbf{n}:
Distance=∣EF⃗⋅n^∣\text{Distance} = |\vec{EF} \cdot \hat{\mathbf{n}}|
=∣16(1−32)⋅112+(−1)2+12(1−11)∣= \left| \frac{1}{6} \begin{pmatrix} 1 \\ -3 \\ 2 \end{pmatrix} \cdot \frac{1}{\sqrt{1^2 + (-1)^2 + 1^2}} \begin{pmatrix} 1 \\ -1 \\ 1 \end{pmatrix} \right|
=163∣(1)(1)+(−3)(−1)+(2)(1)∣= \frac{1}{6\sqrt{3}} \left| (1)(1) + (-3)(-1) + (2)(1) \right|
=163(1+3+2)= \frac{1}{6\sqrt{3}} (1 + 3 + 2)
=663=13=33 units= \frac{6}{6\sqrt{3}} = \frac{1}{\sqrt{3}} = \frac{\sqrt{3}}{3} \text{ units}

Answer

33\frac{\sqrt{3}}{3}

6(iv)

1. Find the displacement vectors for the bonds from the central atom $E$ to atoms $A$ and $C$.

EA→=OA→−OE→=(234)−(112)=(122)\overrightarrow{EA} = \overrightarrow{OA} - \overrightarrow{OE} = \begin{pmatrix} 2 \\ 3 \\ 4 \end{pmatrix} - \begin{pmatrix} 1 \\ 1 \\ 2 \end{pmatrix} = \begin{pmatrix} 1 \\ 2 \\ 2 \end{pmatrix}

EC→=OC→−OE→=(300)−(112)=(2−1−2)\overrightarrow{EC} = \overrightarrow{OC} - \overrightarrow{OE} = \begin{pmatrix} 3 \\ 0 \\ 0 \end{pmatrix} - \begin{pmatrix} 1 \\ 1 \\ 2 \end{pmatrix} = \begin{pmatrix} 2 \\ -1 \\ -2 \end{pmatrix}

2. Use the scalar product to find the angle between the two vectors.

Let θ\theta be the bond angle. Using the scalar product formula cos⁡θ=EA→⋅EC→∣EA→∣∣EC→∣\cos \theta = \frac{\overrightarrow{EA} \cdot \overrightarrow{EC}}{|\overrightarrow{EA}| |\overrightarrow{EC}|}:

cos⁡θ=(122)⋅(2−1−2)12+22+2222+(−1)2+(−2)2\cos \theta = \frac{ \begin{pmatrix} 1 \\ 2 \\ 2 \end{pmatrix} \cdot \begin{pmatrix} 2 \\ -1 \\ -2 \end{pmatrix} }{ \sqrt{1^2 + 2^2 + 2^2} \sqrt{2^2 + (-1)^2 + (-2)^2} }

cos⁡θ=(1)(2)+(2)(−1)+(2)(−2)3×3\cos \theta = \frac{(1)(2) + (2)(-1) + (2)(-2)}{3 \times 3}

cos⁡θ=−49\cos \theta = \frac{-4}{9}

θ=cos⁡−1(−49)≈116.387∘≈116.4∘ (to 1 d.p.)\theta = \cos^{-1}\left(-\frac{4}{9}\right) \approx 116.387^{\circ} \approx 116.4^{\circ} \text{ (to 1 d.p.)}

Answer

116.4∘116.4^{\circ}

6(7)(ii)

1. Separate the variables

xdydx=y+6xy=y(1+6x)x\frac{dy}{dx}=y+6xy=y(1+6x)
Divide through by xyxy:
1y dy=1+6xx dx=(1x+6)dx\frac{1}{y}\,dy=\frac{1+6x}{x}\,dx=\left(\frac{1}{x}+6\right)dx

2. Integrate both sides and solve for y

∫1y dy=∫(1x+6)dx\int\frac{1}{y}\,dy=\int\left(\frac{1}{x}+6\right)dx
ln⁡∣y∣=ln⁡∣x∣+6x+c\ln|y|=\ln|x|+6x+c
Exponentiating:
y=eln⁡∣x∣+6x+c=Ax e6x(A=±ec)y=e^{\ln|x|+6x+c}=A x\,e^{6x}\quad(A=\pm e^{c})

Answer

y=Ax e6x(where A is an arbitrary constant)y = Ax\,e^{6x}\quad(\text{where }A\text{ is an arbitrary constant})

6(7)(iii)

1. Recall the solution of the differential equation

From part (ii), solving xdydx=y+6xy=y(1+6x)x\dfrac{\mathrm{d}y}{\mathrm{d}x}=y+6xy=y(1+6x) gives
∫1y dy=∫(1x+6)dx\int\frac{1}{y}\,\mathrm{d}y=\int\left(\frac{1}{x}+6\right)\mathrm{d}x
ln⁡∣y∣=ln⁡∣x∣+6x+C  ⇒  y=Axe6x.\ln|y|=\ln|x|+6x+C\;\Rightarrow\; y=Ax e^{6x}.

2. Interpret the long-term behaviour

As the situation continues for many months, x→∞x \to \infty. Since e6x→∞e^{6x} \to \infty, we have y=Axe6x→∞y = Axe^{6x} \to \infty.

Hence the number of people infected keeps increasing without bound — it grows indefinitely. In context this is unrealistic, as the number infected cannot exceed the total population.

Answer

As x→∞x\to\infty, y→∞y\to\infty: the number of people infected increases without limit (grows indefinitely), which is not realistic in practice.

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